Search results for "atomic structure"

showing 9 items of 9 documents

Ab initio calculations of pure and Co+2-doped MgF2 crystals

2020

This research was partly supported by the Kazakhstan Science Project № AP05134367«Synthesis of nanocrystals in track templates of SiO2/Si for sensory, nano- and optoelectronic applications», as well as by Latvian Research Council project lzp-2018/1-0214. Calculations were performed on Super Cluster (LASC) in the Institute of Solid State Physics (ISSP) of the University of Latvia. Authors are indebted to S. Piskunov for stimulating discussions.

AB INITIO CALCULATIONSNuclear and High Energy PhysicsMaterials scienceSpin statesBand gapAb initioENERGY GAP02 engineering and technologyFLUORINE COMPOUNDS01 natural sciences7. Clean energyMolecular physicsAb initio quantum chemistry methodsCobalt dopant0103 physical sciencesPhysics::Atomic and Molecular Clusters:NATURAL SCIENCES:Physics [Research Subject Categories]MgF2010306 general physicsFluorideInstrumentationCOBALT DOPANTSDopantCRYSTAL ATOMIC STRUCTUREDopingCOBALT COMPOUNDSMAGNESIUM COMPOUNDSDOPANT ENERGY LEVELS021001 nanoscience & nanotechnologyVIBRATIONAL STRUCTURESCALCULATIONSCRYSTALSGROUND STATELinear combination of atomic orbitalsCELL PROLIFERATIONAb initioGROUND STATE LEVELS0210 nano-technologyGround state
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Evidence of noncentrosymmetry of human tooth hydroxyapatite crystals

2014

Herein, we investigate human single hydroxyapatite crystals (enamel and dentine) by convergent-beam electron diffraction (CBED) and automated electron-diffraction tomography (ADT). The CBED pattern shows the absence of the mirror plane perpendicular to the c axis leading to the P63 space group instead of the P63 /m space group considered for larger-scale crystals, this is confirmed by ADT. This experimental evidence is of prime importance for understanding the morphogenesis and the architectural organization of calcified tissues.

AdultMaleatomic structuresCatalysisX-Ray DiffractionHuman toothmedicineHydroxidesHumansDental Enamelatomic structures; biomineralization; human tooth crystals; noncentrosymmetry; piezoelectricityEnamel paintpiezoelectricityChemistryOrganic ChemistrySpectrometry X-Ray EmissionGeneral Chemistrybiomineralizationnoncentrosymmetrystomatognathic diseasesCrystallographymedicine.anatomical_structureDurapatiteElectron diffractionvisual_artDentinvisual_art.visual_art_mediumNanoparticleshuman tooth crystalsFemaleMirror plane
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Exploring the atomic structure of 1.8 nm monolayer-protected gold clusters with aberration-corrected STEM

2017

Abstract Monolayer-protected (MP) Au clusters present attractive quantum systems with a range of potential applications e.g. in catalysis. Knowledge of the atomic structure is needed to obtain a full understanding of their intriguing physical and chemical properties. Here we employed aberration-corrected scanning transmission electron microscopy (ac-STEM), combined with multislice simulations, to make a round-robin investigation of the atomic structure of chemically synthesised clusters with nominal composition Au 144 (SCH 2 CH 2 Ph) 60 provided by two different research groups. The MP Au clusters were “weighed” by the atom counting method, based on their integrated intensities in the high …

Icosahedral symmetrymonolayer-Protected Gold Clusters02 engineering and technology010402 general chemistry01 natural sciencesMolecular physicsatomic structureatom counting methodMonolayerScanning transmission electron microscopyAu144(SR)60ta116InstrumentationQuantumaberration-Corrected STEMRange (particle radiation)ta114Chemistry021001 nanoscience & nanotechnologyDark field microscopyAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic MaterialsAmorphous solidExponentAtomic physics0210 nano-technologyUltramicroscopy
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New Developments in the Production and Research of Actinide Elements

2022

Atoms 10(2), 61 (2022). doi:10.3390/atoms10020061

Nuclear and High Energy Physicsatomic structure theory; optical spectroscopy; actinides and transactinides; atomic and nuclear properties; thorium-229; trace analysisddc:530Condensed Matter Physics530Atomic and Molecular Physics and Optics
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Phase Stability of Lanthanum Orthovanadate at High Pressure

2016

The journal of physical chemistry / C 120(25), 13749 - 13762(2016). doi:10.1021/acs.jpcc.6b04782

Phase transitionAtomsPhononFOS: Physical scienceschemistry.chemical_elementCrystal atomic structure02 engineering and technologyCrystal structure010402 general chemistry01 natural sciencesMolecular physicssymbols.namesakeCondensed Matter::Materials ScienceAb initio quantum chemistry methodsPhase (matter)Physics - Chemical PhysicsLanthanumPhysical and Theoretical ChemistryAtoms; Calculations; Crystal atomic structureChemical Physics (physics.chem-ph)Condensed Matter - Materials ScienceChemistryMaterials Science (cond-mat.mtrl-sci)021001 nanoscience & nanotechnology5400104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyGeneral Energyddc:540symbols0210 nano-technologyRaman spectroscopyCalculationsMonoclinic crystal system
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Density functional/molecular dynamics simulations of phase-change materials

2013

computer memory materialsrakennecrystallizationamorphoustiheysfunktionaaliteoriakiteytyminenphase-change materialsfaasimuutosmateriaalisemiconductormolecular dynamicsvitrificationchalcogenideatomic structureatomirakennepuolijohteetkalkogenidimolekyylidynamiikkacomputer simulationscrystallinesimulointimuistitdensity functional theory
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Local Structure Studies of Ti for SrTi16O3 and SrTi18O3 by Advanced X-ray Absorption Spectroscopy Data Analysis

2015

Strontium titanate is a model quantum paraelectric in which in the region of dominating quantum statistics the ferroelectric instability is inhibited due to nearly complete compensation of the harmonic contribution into ferroelectric soft mode frequency by the zero-point motion contribution. The enhancement of atomic masses by the substitution of 18O for 16O decreases the zero-point atomic motion and low-T ferroelectricity in SrTi18O3 is realized. In this study we report on the local structure of Ti in SrTi16O3 and SrTi18O3 by Ti K-edge extended x-ray absorption fine structure measurements in temperature range 6 – 300 K.

isotopic effectX-ray absorption spectroscopylocal atomic structureMaterials scienceCondensed matter physicsX-ray absorption spectroscopySoft modesDielectricAtmospheric temperature rangeCondensed Matter PhysicsFerroelectricityAtomic massElectronic Optical and Magnetic Materialsphase transitionsquantum paraelectricchemistry.chemical_compoundCondensed Matter::Materials ScienceNuclear magnetic resonancechemistryStrontium titanateStrontium titanateAbsorption (electromagnetic radiation)
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ODS tērauda izejmateriālu lokālās struktūras analīze izmantojot Ti un Y K-malas rentgenabsorbcijas spektroskopiju

2017

Šajā darbā tika izmantota rentgenstaru absorbcijas spektru analīze oksīdu stiprinātam tēraudam (ODS), kas ir perspektīvs materiāls dažādās jomās, piemēram, saules elektrostacijās, reaktīvos dzinējos, ķīmiskos reaktoros un kodolreaktoros, jo materiālam piemīt tādas īpašības kā laba siltumvadītspēja un zema termiskās izplešanās apvienojumā ar augstu temperatūras izturību, korozijas un radiācijas pretestību. Darbā tiek iegūta informācija par ar dažādām metodēm izgatavotu ODS tēraudu lokālās atomārās struktūras izmaiņu ap itrija (Y) un titāna (Ti) atomiem, analizējot Y un Ti absorbcijas K-malu.

local atomic structureODS steelsFizikax-ray absorption spectroscopymechanical alloyingSTARS
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ODS tērauda izejmateriālu lokālās struktūras analīze, izmantojot rentgenabsorbcijas spektroskopiju

2015

Oksīdu stiprināts tērauds (ODS) ir perspektīvs kodolsintēzes reaktoru materiāls, kuram ir lieliska siltumvadītspēja un zema termiskās izplešanās, apvienojumā ar augstu temperatūras izturību, korozijas un radiācijas pretestību. Tamdēļ šo materiālu var izmantot arī daudzos citos pielietojumos, piemēram, saules elektrostacijās, reaktīvos dzinējos, ķīmiskos reaktoros, kā arī ūdeņraža ražošanā. Šajā darbā ar rentgenabsorbcijas spektroskopijas metodi tika analizētas ferīta un austentisko ODS tēraudu lokālās atomārās struktūras izmaiņas ap dzelzs (Fe) un hroma (Cr) atomiem dažādos tēraudu izgatavošanas posmos, analizējot Fe un Cr absorbcijas K-malas spektrus.

local atomic structurerentgenabsorbcijas spektroskopijalokālā atomārā struktūraODS tēraudsFizikax-ray absorption spectroscopy
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